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The purpose of this study was to investigate how autoignition leads to the occurrence of pressure oscillations. That was done on the basis of in-cylinder visualization and analysis of flame images captured with a high-speed camera using an optically accessible engine, in-cylinder pressure measurement and measurement of light emission from formaldehyde (HCHO). The results revealed that knocking intensity tended to be stronger with a faster localized growth speed of autoignition. An investigation was also made of the effect of exhaust gas recirculation (EGR) as a means of reducing knocking intensity. The results showed that the application of EGR advanced the ignition timing, thereby reducing knocking intensity under the conditions where knocking occurred.

Suppression or reduction of soot emissions is an important goal in the development of automotive engines for environmental and human health purposes. A better understanding at the molecular level of the formation process of soot particles resulting from collision and aggregation of smaller particles made of Polycyclic Aromatic Hydrocarbon (PAH) is needed. In addition to experiments, computational methods are efficient and valuable tools for this purpose. As a first step in our detailed computational chemistry study, we applied Ultra-Accelerated Molecular Dynamics (UAQCMD) and Canonical Monte-Carlo (CMC) methods to investigate the nucleation process. The UA-QCMD can calculate chemical reaction dynamics 107 times faster than conventional first principle molecular dynamics methods, while CMC can calculate equilibrium properties at various temperatures, pressures, and chemical compositions.

A fuel reforming technology using a low temperature oxidation was developed to improve a NOx reduction performance of HC-SCR (Hydrocarbons Selective Catalytic Reduction) system, which does not require urea. The low-temperature oxidization of a diesel fuel in gas phase produces NOx reduction agents with high NOx reduction ability such as aldehydes and ketones. A pre-evaporation-premixing-type reformer was adopted in order to generate a uniform temperature field and a uniform fuel/air premixed gas, and to promote the low temperature oxidation efficiently. As a fundamental study, elementary reaction analysis for n-hexadecane/air premixtures was carried out to investigate the suitable reformer temperature and fuel/air equivalence ratio for generation of oxygenated hydrocarbons. It was found that the reforming efficiency was highest at the reforming temperature around 623 to 673K, and aldehydes and ketones were produced.

Effects of measurement method, coolant temperature and fuel composition on soot emissions were examined by engine experiments. By reducing the pressure fluctuation in the sampling line, the measured soot emissions with better stability and reproducibility could be obtained. With lower coolant temperatures, larger soot emissions were yielded at much advanced fuel injection timings. Compared to gasoline, soot emissions with a blend fuel of normal heptane, isooctane and toluene were significantly decreased, suggesting the amounts of aromatic components (toluene or others) should be increased to obtain a representative fuel for the predictive model of particulate matter in SIDI engines.

The influence of the eddy scale of initial turbulence in RCM on the pressure rise rate after spontaneous ignition of end gas was investigated. The combustion time of the end gas after spontaneous ignition was observed by using high-speed direct photography. As a result, the large scale eddy reduced the pressure rise rate after spontaneous ignition. The temperature inhomogeneity of end gas was higher with the large scale eddy. The combustion time of end gas after spontaneous ignition was prolonged by variation in local ignition delay due to inhomogeneity. The large scale eddy may prevented the knocking occurrence.

In this study, the heated fuels were provided to the diesel engine in order to activate the fuel before the injection. Two test fuels: the normal diesel fuel and cetane, which have different boiling points were used. For both normal diesel fuel and cetane, crank angles at ignition and maximum pressure are delayed and the maximum combustion pressure is decreased as the fuel temperature rises. In cases of large and middle mass flow rate of fuel injection, the brake thermal efficiency and brake mean effective pressure are decreased when the fuel temperature is higher than 570 [K]. However, in the case of small mass flow rate of fuel injection, the brake thermal efficiency is almost independent of fuel temperature. HC and CO concentrations in the exhaust gas emission show constant values regardless of fuel temperature. However, NOx concentration is gradually decreased as the fuel temperature rises.

The aim of this research was to investigate the mechanism causing autoignition and the effect of exhaust gas recirculation (EGR) on combustion by detecting the behavior of the OH radical and other excited molecules present in the flame in a spark ignition engine. The test equipment used was a 2-cycle engine equipped with a Schnürle scavenging system. Using emission spectroscopy, the behavior of the OH radical was measured at four locations in the end zone of the combustion chamber. The OH radical plays an important role in the elemental reactions of hydrocarbon fuels. When a certain level of EGR was applied according to the engine operating conditions, the unburned gas became active owing to heat transfer from residual gas near the measurement positions on the exhaust port side and the influence of excited species in the residual gas, and autoignition tended to occur.

The use of a higher compression ratio is desirable for improving the thermal efficiency and specific power of spark-ignition engines, but it gives rise to a problem of engine knock. In the present research, an investigation was made of the role of the preflame reaction region of a spark-ignition engine in the occurrence of autoignition. Emission spectroscopy was used to measure the behavior of formaldehyde (HCHO) in a cool flame. In addition, measure the behavior of the faint light attributed to the HCO radical in a blue flame with the concurrent measurement of the OH radical. The emission waveforms measurements obtained for HCHO when n-heptane (ORON) was used as the fuel, It is thought that these tendencies correspond to the passage and degeneracy of a cool flame. Further, the emission waveforms measured for the HCO radical when blended fuels (6ORON, 8ORON) were correspond to that of a blue flame.

This study focused on a non-equilibrium plasma discharge as a means of assisting HCCI combustion.Experiments were conducted with a four-stroke single-cylinder engine fitted with a spark electrode in the top of the combustion chamber for continuously generating non-equilibrium plasma from the intake stroke to the exhaust stroke. The results showed that applying non-equilibrium plasma to the HCCI test engine advanced the main combustion period that otherwise tended to be delayed as the engine speed was increased. In addition, it was found that the combined use of exhaust gas recirculation and non-equilibrium plasma prevented a transition to partial combustion while suppressing cylinder pressure oscillations at high loads.

This study investigated the effects of recirculated exhaust gas (EGR) and its principal components of N2, CO2 and H2O on moderating Homogeneous Charge Compression Ignition (HCCI) combustion. Experiments were conducted using two types of gaseous fuel blends of DME/propane and DME/methane as the test fuels. The addition rates of EGR, N2, CO2 and H2O were varied and the effects of each condition on HCCI combustion of propane and methane were investigated. The results revealed that the addition of CO2 and H2O had the effect of substantially delaying and moderating rapid combustion. The addition of N2 showed only a slight delaying and moderating effect. The addition of EGR had the effect of optimally delaying the combustion timing, while either maintaining or increasing the indicated mean effective pressure and indicated thermal efficiency ηi.

The purpose of this study is to explore an effect of the coconut oil methyl ester (CME) and vegetable oil methyl ester (VME) on a low compression ratio diesel engine performance. CME and VME were produced from coconut oil and vegetable oil with methanol, respectively. Vegetable oil was assumed to contain 60 wt.% of soybean oil and 40 wt.% rapeseed oil. The engine performance was measured in the steady operating condition at 3600 rpm of engine speed. The ignition timings of CME and VME were advanced and the maximum cylinder pressures of CME and VME were higher as compared with the diesel fuel at low compression ratio, because CME and VME consisted of medium chain fatty acid methyl esters. The ignitability of CME was superior to VME, because CME consisted of saturated fatty acid. The brake thermal efficiency of diesel fuel was slightly higher than CME and VME at any compression ratios.

Homogeneous Charge Compression Ignition (HCCI) combustion has attracted widespread interest because it achieves high efficiency and can reduce particulate matter (PM) and nitrogen oxide (NOx) emissions simultaneously. However, because HCCI engines lack a physical means of initiating ignition, it is difficult to control the ignition timing. Another issue of HCCI engines is that the combustion process causes the cylinder pressure to rise rapidly. The time scale is also important in HCCI combustion because ignition depends on the chemical reactions of the mixture. Therefore, we investigated the influence of the engine speed on autoignition and combustion characteristics in an HCCI engine. A four-stroke single-cylinder engine equipped with a mechanically driven supercharger was used in this study to examine HCCI combustion characteristics under different engine speeds and boost pressures.

Unresolved issues of Homogeneous Charge Compression Ignition (HCCI) combustion include an extremely rapid pressure rise on the high load side and resultant knocking. Studies conducted to date have examined ways of expanding the region of stable HCCI combustion on the high load side such as by applying supercharging or recirculating exhaust gas (EGR). However, the effect of applying EGR gas to supercharged HCCI combustion and the mechanisms involved are not fully understood. In this study, the effect of EGR gas components on HCCI combustion was investigated by conducting experiments in which external EGR gas was applied to supercharged HCCI combustion and also experiments in which nitrogen (N2) and carbon dioxide (CO2) were individually injected into the intake air pipe to simulate EGR gas components. In addition, HCCI combustion reactions were analyzed by conducting chemical kinetic simulations under the same conditions as those of the experiments.

Internal combustion engines today are required to achieve even higher efficiency and cleaner exhaust emissions. Currently, research interest is focused on premixed compression ignition (Homogeneous Charge Compression Ignition, HCCI) combustion. However, HCCI engines have no physical means of initiating ignition such as a spark plug or the fuel injection timing and quantity. Therefore, it is difficult to control the ignition timing. In addition, combustion occurs simultaneously at multiple sites in the combustion chamber. As a result, combustion takes place extremely rapidly especially in the high load region. That makes it difficult for the engine to operate stably at high loads. This study focused on the fuel composition as a possible means to solve these problems. The effect of using fuel blends on the HCCI operating region and combustion characteristics was investigated using a single-cylinder test engine.

The purpose of this study is to explore an effect of cooled-EGR on the diesel engine performance fueled with coconut-oil methyl ester (CME). The exhaust gas was cooled by the water at room temperature and was fed to the intake manifold, and the EGR rate was changed from 0 % to 30 % at every 10 %. The engine performances were measured at several EGR rates, fuel injection pressures and timings. Test fuels were CME and commercial diesel fuel. In the case of high EGR rate at which the compression ignition was deteriorated, the ignition timing of CME was always earlier than that of diesel fuel, therefore CME had good ignitability as compared with diesel fuel under EGR application. When the fuel injection pressure was increased at high EGR rate, the ignition delay was improved by the fuel atomization and air-fuel mixing effect.